Sulfur-containing palladacycles as catalyst precursors for the Heck reaction

Authors
Gruber, AS Zim, D Ebeling, G Monteiro, AL Dupont, J
Citation
As. Gruber et al., Sulfur-containing palladacycles as catalyst precursors for the Heck reaction, ORG LETT, 2(9), 2000, pp. 1287-1290
Citations number
26
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANIC LETTERS
ISSN journal
15237060 → ACNP
Volume
2
Issue
9
Year of publication
2000
Pages
1287 - 1290
Database
ISI
SICI code
1523-7060(20000504)2:9<1287:SPACPF>2.0.ZU;2-B
Abstract
The air, water, and highly thermally stable sulfur-containing palladacycles , mainly derived from the ortho-palladation of benzylic thioethers, are exc eptional catalyst precursors for the Heck reaction. The reaction can be per formed with aryl iodides, bromides, and chlorides, with acrylic esters and styrene, leading to turnover numbers up to 1 850 000.