Dinitrogen cleavage stemming from a heterodinuclear niobium/molybdenum N-2complex: New nitridoniobium systems including a niobazene cyclic trimer

Authors
Mindiola, DJ Meyer, K Cherry, JPF Baker, TA Cummins, CC
Citation
Dj. Mindiola et al., Dinitrogen cleavage stemming from a heterodinuclear niobium/molybdenum N-2complex: New nitridoniobium systems including a niobazene cyclic trimer, ORGANOMETAL, 19(9), 2000, pp. 1622-1624
Citations number
36
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
19
Issue
9
Year of publication
2000
Pages
1622 - 1624
Database
ISI
SICI code
0276-7333(20000501)19:9<1622:DCSFAH>2.0.ZU;2-Z
Abstract
Preparation of the terminal nitrido anion (-)[NNb(N[Pr-i]Ar)(3)] and the ni obazene trimer {(mu-N)Nb-(N[Pr-i]Ar)(2)}(3) (Pr-i = CH(CH3)(2) or CH(CD3)(2 ), Ar = 3,5-C6H3Me2) entails cooperative splitting of dinitrogen upon reduc tion of the heterobimetallic paramagnetic dinitrogen complex (Ar[R]N)(3)Mo( mu-N-2)Nb(N[Pr-i]Ar)(3) (R = Bu-t or C(CD3)(2) CH3).