A method based on Kelvin probe force microscopy for measuring minority-carr
ier diffusion length in semiconductors is described. The method is based on
measuring the surface photovoltage between the tip of an atomic farce micr
oscope and the surface of an illuminated semiconductor junction. The photog
enerated carriers diffuse to the junction and change the contact potential
difference between the tip and the sample, as a function of the distance fr
om the junction. The diffusion length L is then obtained by fitting the mea
sured contact potential difference using the minority-carrier continuity eq
uation. The method was applied to measurements of electron diffusion length
in GaP pn and Schottky junctions. The measured diffusion length was found
to be similar to 2 mu m, in good agreement with electron beam induced curre
nt measurements.