We have investigated the ripening of breath figures with variable initial o
rder. A dramatic impact of the degree of order on the coalescence behavior
is observed. As opposed to the two-droplet coalescence events common to the
usual disordered droplet arrays, four-droplet coalescence cascades predomi
nate in a perfectly hexagonal breath figure. Upon introduction of disorder,
a gradual transition to a regime dominated by three-droplet cascades is ob
served. The statistics of coalescence cascades allows for detailed conclusi
ons on the microscopic droplet dynamics.