Authors
Citation
Aa. Khodyakov et Vv. Gromov, Formation of point defects in alkali metal borate and alkali metal phosphate electrochromic glasses, RUSS J PH C, 73(9), 1999, pp. 1515-1518
Citations number
6
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY
ISSN journal
00360244
→ ACNP
Volume
73
Issue
9
Year of publication
1999
Pages
1515 - 1518
Database
ISI
SICI code
0036-0244(199909)73:9<1515:FOPDIA>2.0.ZU;2-7
Abstract
An EPR analysis shows that, in gamma-irradiated Me2O-P2O5-WO3 and Me2O-B2O3
-WO3 (Me = Li, Na, K, and Rb) glasses, PO32-, PO42-, BO32-,W5+, and O-2(-)
point defects and atomic hydrogen (from structurally bound water) are forme
d. For these glasses, the radiochemical yield of atomic hydrogen increases
with the alkali metal cation radius from Li to Rb.