The enthalpy of extracoordination of imidazole by some metalloprotoporphyrins

Authors
Berezin, MB Chernova, OM
Citation
Mb. Berezin et Om. Chernova, The enthalpy of extracoordination of imidazole by some metalloprotoporphyrins, RUSS J PH C, 73(8), 1999, pp. 1191-1194
Citations number
13
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY
ISSN journal
00360244 → ACNP
Volume
73
Issue
8
Year of publication
1999
Pages
1191 - 1194
Database
ISI
SICI code
0036-0244(199908)73:8<1191:TEOEOI>2.0.ZU;2-G
Abstract
The enthalpies of solution of deutero- and hematoporphyrin and their comple xes with Zn(II) and Cd(II) in benzene, chloroform, and tetrachloromethane w ith imidazole admixtures were measured calorimetrically at 298.15 K. The en thalpy contribution of imidazole extracoordination by metalloporphyrins was estimated. The influence of structural characteristics of the solvation sh eaths of porphyrins on the enthalpy characteristics of interparticle intera ctions is discussed.