Ai. Gorichev et al., The influence of nonaqueous solvents on the kinetics of solution of magnetite in hydrochloric acid, RUSS J PH C, 73(7), 1999, pp. 1087-1093
The kinetics of solution of magnetite was studied as functions of the conce
ntrations of hydrochloric acid and nonaqueous solvents. Methods for calcula
ting the kinetic constants based on heterogeneous and electrochemical kinet
ics principles and a model mechanism of solution of magnetite taking into a
ccount the acid-base and adsorption properties of magnetite were suggested.
Stimulating effects of nonaqueous solvents on the kinetic processes were e
xplained by changes in the potential at the oxide/electrolyte interface.