The thermodynamic functions of trimethylsilylethyleneimine in the temperature range 0-310 K

Citation
Tg. Kulagina et Bv. Lebedev, The thermodynamic functions of trimethylsilylethyleneimine in the temperature range 0-310 K, RUSS J PH C, 73(12), 1999, pp. 1909-1913
Citations number
14
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY
ISSN journal
00360244 → ACNP
Volume
73
Issue
12
Year of publication
1999
Pages
1909 - 1913
Database
ISI
SICI code
0036-0244(199912)73:12<1909:TTFOTI>2.0.ZU;2-M
Abstract
The temperature dependence of the heat capacity of trimethylsilylethyleneim ine was determined accurate to similar to 0.2% in the temperature range 5-3 10 K with the use of an adiabatic vacuum calorimeter. The temperature and t he enthalpy of fusion of the substance were determined. The experimental da ta were used to calculate the thermodynamic functions in the temperature ra nge 0-310 K. The isochoric heat capacity and its lattice and atomic compone nts were estimated.