The role played by the branched-chain mechanism in combustion and explosion at atmospheric and higher pressures

Authors
Citation
Vv. Azatyan, The role played by the branched-chain mechanism in combustion and explosion at atmospheric and higher pressures, RUSS J PH C, 73(10), 1999, pp. 1577-1589
Citations number
83
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY
ISSN journal
00360244 → ACNP
Volume
73
Issue
10
Year of publication
1999
Pages
1577 - 1589
Database
ISI
SICI code
0036-0244(199910)73:10<1577:TRPBTB>2.0.ZU;2-1
Abstract
The special features of branched-chain processes were analyzed to show that , in contrast to views commonly accepted until recently, competition betwee n chain branching and termination plays the determining role in combustion and explosion of hydrogen-containing and many other compounds not only at p ressures tens and hundreds times lower than atmospheric but also at atmosph eric and higher pressures. This point opens new horizons in developing the chain process theory and governing the combustion processes. Data illustrat ing the existence of two chain combustion modes are presented.