A theoretical calculation of the limiting equivalent conductivity of solutions of single-charged monoatomic ions in water and various organic solvents

Authors
Kuznetsova, EM Kirsanov, RS
Citation
Em. Kuznetsova et Rs. Kirsanov, A theoretical calculation of the limiting equivalent conductivity of solutions of single-charged monoatomic ions in water and various organic solvents, RUSS J PH C, 73(10), 1999, pp. 1596-1601
Citations number
18
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY
ISSN journal
00360244 → ACNP
Volume
73
Issue
10
Year of publication
1999
Pages
1596 - 1601
Database
ISI
SICI code
0036-0244(199910)73:10<1596:ATCOTL>2.0.ZU;2-R
Abstract
A new model qualitatively describing the limiting equivalent conductivity o f ionic solutions lambda(i)(o) is proposed. The model makes it possible to calculate desired characteristics only from the properties of the solvent, ionic crystal radii, and masses of the ions, without using fitting paramete rs. The adequacy of the model is tested by calculating lambda(i)(o) values for aqueous solutions and fourteen organic solvents belonging to various cl asses.