Optical absorption and emission spectra of 1,1,2,2,9,9,10,10-octafluoro[2,2]paracyclophane

Authors
Nurmukhametov, RN Volkova, LV Mailyan, KA Pebalk, AV Kardash, IE Takakhashi, A
Citation
Rn. Nurmukhametov et al., Optical absorption and emission spectra of 1,1,2,2,9,9,10,10-octafluoro[2,2]paracyclophane, RUSS J PH C, 73(10), 1999, pp. 1676-1679
Citations number
12
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY
ISSN journal
00360244 → ACNP
Volume
73
Issue
10
Year of publication
1999
Pages
1676 - 1679
Database
ISI
SICI code
0036-0244(199910)73:10<1676:OAAESO>2.0.ZU;2-P
Abstract
The absorption and fluorescence spectra of 1,1,2,2,9,9,10,10-octafluoro[2,2 ]paracyclophane were studied. The influence on the absorption spectra of th e replacement of hydrogen (H) atoms by fluorine (F) in CH2-CH2 bridges was analyzed. The main reason for changes in the absorption spectrum of 1,1,2,2 ,9,9,10,10-octafluoro[2,2]paracyclophane with respect to the spectrum of [2 ,2]paracyclophane was shown to be spatial effects of fluoro substitution.