Calculation of the coefficient of distribution of admixtures between the gas phase and gas hydrates

Citation
Vm. Vorotyntsev et Vm. Malyshev, Calculation of the coefficient of distribution of admixtures between the gas phase and gas hydrates, RUSS J PH C, 73(10), 1999, pp. 1704-1707
Citations number
10
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY
ISSN journal
00360244 → ACNP
Volume
73
Issue
10
Year of publication
1999
Pages
1704 - 1707
Database
ISI
SICI code
0036-0244(199910)73:10<1704:COTCOD>2.0.ZU;2-4
Abstract
A model of ideal clathrate solutions was developed to treat the formation o f gas hydrates in gas mixtures. A relative distribution coefficient is intr oduced to characterize the distribution of the gas components between the s olid and gas phases. It is shown that the degree of concentration of an ind ividual impurity (and the relative distribution coefficient) largely depend s on the composition of the gas mixture, its temperature, and pressure. The conditions of formation of hydrates and the characteristics of the redistr ibution of components typical of industrial emergence emissions into the at mosphere are evaluated. It is found that hydrates largely contain industria l pollutants.