CO LMR spectrum of (NO)-N-14-O-16 and its analysis with spectra of (NO)-N-14-O-17 and (NO)-N-14-O-18

Citation
Yy. Liu et al., CO LMR spectrum of (NO)-N-14-O-16 and its analysis with spectra of (NO)-N-14-O-17 and (NO)-N-14-O-18, SCI CHINA B, 43(2), 2000, pp. 121-128
Citations number
35
Categorie Soggetti
Chemistry
Journal title
SCIENCE IN CHINA SERIES B-CHEMISTRY
ISSN journal
1001652X → ACNP
Volume
43
Issue
2
Year of publication
2000
Pages
121 - 128
Database
ISI
SICI code
1001-652X(200004)43:2<121:CLSO
Abstract
LMR spectra for v=1<--0 transitions of (NO)-N-14-O-16 in X(2)Pi(1/2,3/2) st ates were observed at 5.6 mu m and 5.4 mu m of CO laser. Introducing the ad vanced isotopic molecular constant scaling function to Hund's case (a) diat omic structure model, these spectra were analyzed and fitted together with all reliable previous spectral data of (NO)-N-14-O-16 as well as (NO)-N-14- O-17 and (NO)-N-14-O-18. A full set of precise molecular parameters and the ir vibrational dependencies have been determined with much higher precision (1-2 orders for most parameters). Many of them have been obtained for the first time. Using isotopic scaling function, the molecular constants of (NO )-N-14-O-17 and (NO)-N-14-O-18 were deduced.