Reactivity of CFn (n=1-3) species with a silica surface

Authors
Ricca, A
Citation
A. Ricca, Reactivity of CFn (n=1-3) species with a silica surface, SURF SCI, 452(1-3), 2000, pp. 117-124
Citations number
16
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
SURFACE SCIENCE
ISSN journal
00396028 → ACNP
Volume
452
Issue
1-3
Year of publication
2000
Pages
117 - 124
Database
ISI
SICI code
0039-6028(20000501)452:1-3<117:ROC(SW>2.0.ZU;2-#
Abstract
The trends in reactivity of CFn neutrals with a silica surface are studied using two different cluster models. CF appears to be the most reactive spec ies. The energetics, the activation energies, and the forward reaction rate s are computed for two reactions involving the Si-O bond breaking. (C) 2000 Elsevier Science B.V. All rights reserved.