Synthesis and spectroscopic characterization of dibutylgermanium(IV) complexes of 2-amino-cyclopentene-1-carbodithioic acid and its N-/S-alkyl derivatives

Authors
Sharma, RK Singh, YP Rai, AK
Citation
Rk. Sharma et al., Synthesis and spectroscopic characterization of dibutylgermanium(IV) complexes of 2-amino-cyclopentene-1-carbodithioic acid and its N-/S-alkyl derivatives, SYN REAC IN, 30(4), 2000, pp. 695-707
Citations number
27
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
ISSN journal
00945714 → ACNP
Volume
30
Issue
4
Year of publication
2000
Pages
695 - 707
Database
ISI
SICI code
0094-5714(2000)30:4<695:SASCOD>2.0.ZU;2-#
Abstract
Dibutylgermanium(IV) complexes of the type [GRAPHICS] (where R = H, CH3, C2H5 and C4H9) and [GRAPHICS] have been prepared by the reaction of dibutylgermanium(IV) dichloride with the sodium salts of N-/S-alkyl derivatives of 2-aminocyclopentene-1-carbodi thioic acid in 1:2 molar ratio in benzene solution. All of these derivative s have been characterized by elemental analyses, spectroscopic (IR, H-1 and C-13 NMR) studies as well as by molecular weight determinations.