Synthesis and crystal structures of two nest-shaped cluster compounds, [MoOS3Cu3(SCN)py(5)] and [WOS3Cu3(SCN)py(5)]

Authors
Zheng, HG Chen, JX Xin, XQ Leung, WH Hong, MC
Citation
Hg. Zheng et al., Synthesis and crystal structures of two nest-shaped cluster compounds, [MoOS3Cu3(SCN)py(5)] and [WOS3Cu3(SCN)py(5)], SYN REAC IN, 30(4), 2000, pp. 761-775
Citations number
32
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
ISSN journal
00945714 → ACNP
Volume
30
Issue
4
Year of publication
2000
Pages
761 - 775
Database
ISI
SICI code
0094-5714(2000)30:4<761:SACSOT>2.0.ZU;2-5
Abstract
The compounds [MOS3Cu3(SCN)X-5] (M = Mo, W; X = py, 4-CH(3)py, 4-tert-Bupy) have been prepared by the reaction of(NH4)(2)MO2S2 (M = MO, W), CuSCN and the appropriate ligand X under mild conditions and were characterized by el emental analyses, LR and UV-Vis spectra. Single-crystal X-ray analyses of b oth compounds reveal that they have a nest-shaped structure and the average M-Cu distances are 2.684(3) Angstrom for M = Mo and 2.693(2) Angstrom for M = W.