N,N '-bis(2-tosylaminobenzylidene)-benzene-1,2-diamine

Citation
J. Mahia et al., N,N '-bis(2-tosylaminobenzylidene)-benzene-1,2-diamine, ACT CRYST C, 56, 2000, pp. 492-493
Citations number
11
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
56
Year of publication
2000
Part
4
Pages
492 - 493
Database
ISI
SICI code
0108-2701(200004)56:<492:N'>2.0.ZU;2-F
Abstract
The conformation of the title compound, C34H30N4O4S2, is strongly influence d by intramolecular N-H ... N hydrogen-bond interactions and by the rigidit y endowed by the presence of a phenyl group between the imine N atoms. The molecule is not planar, with very short distances between the imine N atoms [N ... N 2.753 (3) Angstrom] and the amine N atoms [N ... N 5.148 (4) Angs trom] Consequently, important changes in its conformation will be required if it is to act as a tetradentate ligand via its four N atoms.