Ll. Sun et al., Reversible phase transition between amorphous and crystalline in Zr41.2Ti13.8Cu12.5Ni10Be22.5 under high pressure at room temperature, APPL PHYS L, 76(20), 2000, pp. 2874-2876
A reversible phase transition between amorphous and crystalline in bulk met
allic glass (BMG) Zr41.2Ti13.8Cu12.5Ni10Be22.5 has been investigated under
high pressure at room temperature. The BMG displayed a structure memory und
er high pressure as detected by in situ synchrotron radiation of x-ray diff
raction and resistance measurement in a diamond anvil cell. Direct experime
ntal observations found that the crystallization of the BMG occurred at 24
GPa on uploading and the crystalline phase reverted back to the amorphous s
tate during downloading. This unusual phenomenon was discussed thermodynami
cally. (C) 2000 American Institute of Physics. [S0003-6951(00)04220-0].