Preparation of 2-propanol dehydrogenation catalysts for chemical heat pumpsystem

Citation
H. Lee et al., Preparation of 2-propanol dehydrogenation catalysts for chemical heat pumpsystem, B CHEM S J, 73(4), 2000, pp. 1015-1019
Citations number
19
Categorie Soggetti
Chemistry
Journal title
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
ISSN journal
00092673 → ACNP
Volume
73
Issue
4
Year of publication
2000
Pages
1015 - 1019
Database
ISI
SICI code
0009-2673(200004)73:4<1015:PO2DCF>2.0.ZU;2-X
Abstract
2-Propanol dehydrogenation catalysts were prepared using three types of pre paration methods. The catalytic activities of these catalysts were compared through reaction experiments. A Ru catalyst, prepared by an incipient-wetn ess method followed by NaBH4 reduction, had the predominant reaction rate, and a Pt catalyst, prepared by an incipient-wetness method with H-2 reducti on at 400 degrees C, showed high activity. The Ru catalysts with high tempe rature reduction and Pt catalysts with NaBH4 reduction showed negligible re action rates; Also, a catalyst supported on activated carbon had a better a ctivity than that on alumina. The Ru on activated carbon was proper for a c hemical heat-pump system because of higher activity and a lower reduction t emperature than the Pt catalyst.