1,1-dimethylhydrazidogallane and a gallium hydrazide with two Ga2N2 rings bridged by two NNMe2 ligands

Authors
Luo, B Gladfelter, WL
Citation
B. Luo et Wl. Gladfelter, 1,1-dimethylhydrazidogallane and a gallium hydrazide with two Ga2N2 rings bridged by two NNMe2 ligands, CHEM COMMUN, (10), 2000, pp. 825-826
Citations number
13
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
10
Year of publication
2000
Pages
825 - 826
Database
ISI
SICI code
1359-7345(2000):10<825:1AAGHW>2.0.ZU;2-T
Abstract
Volatile, thermally robust 1,1-dimethylhydrazidogallane, [H2GaN(H)NMe2](2) 1 has been synthesized from the reaction of H3Ga(NMe3) with H2NNMe2, wherea s reaction of compound 1 with an excess of H2NNMe2 at elevated temperature afforded a gallium hydrazide derivative, Ga-4[N(H)NMe2](8)(NNMe2)(2) 2, whi ch possessed a novel structure of two Ga2N2 rings bridged by NNMe2 groups.