(eta(6)-arene)ruthenium oxomolybdenum and oxotungsten clusters. Stereochemical non-rigidity of [{Ru(eta(6)-p-MeC6H4Pri)}(4)Mo4O16] and crystal structure of [{Ru(eta(6)-p-MeC6H4Pri)}(4)W2O10]

Authors
Artero, V Proust, A Herson, P Thouvenot, R Gouzerh, P
Citation
V. Artero et al., (eta(6)-arene)ruthenium oxomolybdenum and oxotungsten clusters. Stereochemical non-rigidity of [{Ru(eta(6)-p-MeC6H4Pri)}(4)Mo4O16] and crystal structure of [{Ru(eta(6)-p-MeC6H4Pri)}(4)W2O10], CHEM COMMUN, (10), 2000, pp. 883-884
Citations number
14
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
10
Year of publication
2000
Pages
883 - 884
Database
ISI
SICI code
1359-7345(2000):10<883:(OAOCS>2.0.ZU;2-3
Abstract
According to a multinuclear NMR study, the cluster [{Ru(eta(6)-p-MeC6H4Pri) }(4)Mo4O16] exists as two isomers, the windmill-like form and the triple-cu bane form, which are in equilibrium in solution, while the tungsten analogu e, which has been obtained together with the double-cubane type cluster [{R u(eta(6)-p-MeC6H4Pri)}(4)W2O10] by reaction of [{Ru(eta(6)-p-MeC6H4Pri)Cl-2 }(2)] with (NBu4n)(2)[WO4] in acetonitrile, only displays the windmill-like structure.