Highly-soluble fluorocarbon surfactant in supercritical carbon dioxide: Effect of counter cation on solubility

Citation
T. Kawakami et al., Highly-soluble fluorocarbon surfactant in supercritical carbon dioxide: Effect of counter cation on solubility, CHEM LETT, (4), 2000, pp. 402-403
Citations number
10
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
4
Year of publication
2000
Pages
402 - 403
Database
ISI
SICI code
0366-7022(20000405):4<402:HFSISC>2.0.ZU;2-F
Abstract
We have developed a new series of branch-structured anionic surfactants dis solved significantly well in sc-CO2. We found that, the variation of counte r ion species has a significant effect on the solubility of the surfactants in sc-CO2. Among these, the solubility of surfactant with ammonium ion exc eeded 16 wt% at 40 degrees C and 15 MPa while that of surfactant with K+ wa s neglectable. This effect can be used for complete recovery of the surfact ant.