Synthesis and spectroscopic characterization of a Dawson trivanadium-substituted polyoxotungstate-supported {(Cp*Rh)(2)}(4+) complex; ((Bu4N)-N-n)(5)[(Cp*Rh)(2)P2W15V3O62]

Authors
Nomiya, K Hasegawa, T
Citation
K. Nomiya et T. Hasegawa, Synthesis and spectroscopic characterization of a Dawson trivanadium-substituted polyoxotungstate-supported {(Cp*Rh)(2)}(4+) complex; ((Bu4N)-N-n)(5)[(Cp*Rh)(2)P2W15V3O62], CHEM LETT, (4), 2000, pp. 410-411
Citations number
18
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
4
Year of publication
2000
Pages
410 - 411
Database
ISI
SICI code
0366-7022(20000405):4<410:SASCOA>2.0.ZU;2-9
Abstract
A novel polyoxotungstate-based 2 : 1-type Cp*Rh2+ complex, ((Bu4N)-N-n)(5)[ (Cp*Rh)(2)P2W15V3O62] (Cp* = C5Me5), was synthesized by a direct reaction o f the Dawson trivanadium-substituted polyoxotungstate ((Bu4N)-N-n)(9)[alpha -1,2,3-P2W15V3O62] with an equimolar amount of [Cp*RhCl2](2) in ice-cooled CH2Cl2, without use of silver(I) salts to remove the chloride ions of the p recursor.