The influence of the environment on the tribological properties of diamond
has been studied by investigating the effect on the friction coefficient of
oxygen containing liquids introduced at the interface of contact. A diamon
d stylus was allowed to perform reciprocating movement on a diamond surface
under different loads and sliding velocities. A droplet of the chosen liqu
id was introduced at the interface and the changes in the friction coeffici
ent were recorded. All the liquids tested reduced the value of the friction
coefficient significantly, by an extent which depended on the chemical com
position of the liquid, the load and the sliding velocity. An interpretatio
n of our results is given in terms of the reduction of adhesion due to the
adsorption of these liquids on the surface, and of the possibility of graph
itisation occurring on the surface during sliding. (C) 2000 Elsevier Scienc
e S.A. All rights reserved.