Synthesis and crystal structure of bis(2,3-dihydro-3-methylbenzothiazole-2-ylidene)palladium(II) diiodide: The first palladium complex with benzothiazole carbene ligands suitable for homogeneous catalysis

Authors
Calo, V Del Sole, R Nacci, A Schingaro, E Scordari, F
Citation
V. Calo et al., Synthesis and crystal structure of bis(2,3-dihydro-3-methylbenzothiazole-2-ylidene)palladium(II) diiodide: The first palladium complex with benzothiazole carbene ligands suitable for homogeneous catalysis, EUR J ORG C, (6), 2000, pp. 869-871
Citations number
28
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
ISSN journal
1434193X → ACNP
Issue
6
Year of publication
2000
Pages
869 - 871
Database
ISI
SICI code
1434-193X(200003):6<869:SACSOB>2.0.ZU;2-G
Abstract
The first diiodo palladium complex with nucleophilic benzothiazole carbenes as ligands has been synthesized and characterized. The complex, which is e xtraordinarily stable towards heat, oxygen, and moisture, has been found to show good catalytic activity in the Heck coupling reaction.