Isomerization of matrix-isolated formamide: IR-spectroscopic detection of formimidic acid

Authors
Maier, G Endres, J
Citation
G. Maier et J. Endres, Isomerization of matrix-isolated formamide: IR-spectroscopic detection of formimidic acid, EUR J ORG C, (6), 2000, pp. 1061-1063
Citations number
5
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
ISSN journal
1434193X → ACNP
Issue
6
Year of publication
2000
Pages
1061 - 1063
Database
ISI
SICI code
1434-193X(200003):6<1061:IOMFID>2.0.ZU;2-K
Abstract
Ultraviolet irradiation of matrix-isolated formamide (1) in solid argon wit h light of wavelength 248 nm leads to the formation of formimidic acid (2). Comparison of the experimental IR spectrum of the photoproduct with the ca lculated IR spectrum of 2 shows clearly that two rotamers 2a and 2b are for med.