Application of photoelectron spectroscopy to molecular properties, 57 - UVphotoelectron spectroscopy studies of the products of thermal extrusion ofsulfur dioxide from benzosultams

Citation
A. Chrostowska et al., Application of photoelectron spectroscopy to molecular properties, 57 - UVphotoelectron spectroscopy studies of the products of thermal extrusion ofsulfur dioxide from benzosultams, EUR J ORG C, (2), 2000, pp. 313-318
Citations number
25
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
ISSN journal
1434193X → ACNP
Issue
2
Year of publication
2000
Pages
313 - 318
Database
ISI
SICI code
1434-193X(200001):2<313:AOPSTM>2.0.ZU;2-E
Abstract
An aza-ortho-xylylene system is produced by thermal degradation of N-alkylb enzosultam, which can be directly studied by coupling the system to a UV/ph otoelectron spectrometer. These thermodynamically unstable xylylene derivat ives rearrange to give aldimine by a [1,5] hydrogen shift.