N. Petit et al., Temperature dependence of infrared conductivity of manganites Pr0.7Ca0.3-xSrxMnO3 (x=0, 0.05 and 0.2), EUR PHY J B, 14(4), 2000, pp. 617-625
The temperature dependence of the reflectivity spectra of three manganites
ceramics with compositions Pr0.7Ca0.3MnO3; Pr0.7Ca0.25Sr0.05MnO3 and Pr0.7C
a0.1Sr0.2MnO3 has been investigated by infrared reflectivity spectroscopy i
n the wave number range 0.005-1.1 eV. The compound Pr0.7Ca0.25Sr0.05MnO3 wh
ich shows the largest conductivity jump at the ferromagnetic-paramagnetic p
hase transition has been studied in details. The optical conductivity of th
is compound is deduced from the best fit to reflectivity spectra of a "doub
le-damping Drude" model, itself derived from the factorized form of the die
lectric function. Excellent agreement with Kramers-Kronig transformation is
reported. The model allows in particular to discriminate the contributions
to the optical conductivity of trapped charges (polarons) and mobile charg
e carriers.