Js. Roberts et al., 730 nm InAlGaAsSQW laser diodes grown by MOVPE using 'ether-free' and conventional 'solution' trimethylindium, IEE P-OPTO, 147(1), 2000, pp. 7-9
SQW GRINSCH laser diodes for high power operation at 730 nm have been fabri
cated using atmospheric pressure MOVPE. The SQW InA1GaAs gain region has be
en prepared using two different trimethylindium sources, consisting of eith
er an N N-dimethyldodecylamine : TMI adduct solution of conventionally manu
factured/purified TMI, or solid TMI (diethylether-free synthesis). Both TMI
sources address the reduction of contamination associated with the solvent
diethylether, commonly used in the preparative route to TMI. Furthermore,
devices prepared from ether-free TMI show a lower threshold current and lon
ger lifetime for the same waveguide geometry. The lowering of residual oxyg
en from TMI is thought to be the most likely reason for these material impr
ovements.