The volume-averaged equations for velocity and concentration fields have be
en used to simulate the hydrodynamics and mass-transfer processes in random
ly packed distillation columns. This approach is regarded as a second-gener
ation computational fluid dynamics (CFD) based model, and a significant dep
arture from the traditional one-dimensional, first-generation models. The m
odel has ability to capture radial and axial variations in flow and mass-tr
ansfer conditions. The spatial variation of void fraction has been included
to take into account the effect of bed structures. The simulation results
have been compared with experimental data reported by Fractionation Researc
h, Inc. (FRI) which performed their tests in a 1.22-m-diameter column with
a packed bed height of 3.66 m. For validation, we have used data obtained w
ith 15.9-, 25.4-, and 50.8-mm metal Pall rings at various operating conditi
ons. Good agreement between CFD predictions and published experimental data
has been obtained. This is regarded as an encouraging sign that CFD models
can play a useful role in studying separation processes.