Experimental data on the liquidus curve in cadmium fluoride-metal fluoride
systems were used to calculate the distribution coefficients of di- and tri
valent impurities in CdF2. A similar method was proposed for calculating th
e distribution coefficient from solidus data. It was shown that the variati
ons of the calculated distribution coefficients with the ionic radii of M2 and R3+ are well fitted by Gaussians. Phase relations in the CdF2-rich par
t of the CdF2-InF3 system were studied by differential thermal analysis and
x-ray diffraction.