Distribution coefficients of impurities in cadmium fluoride

Citation
Sp. Ivanov et al., Distribution coefficients of impurities in cadmium fluoride, INORG MATER, 36(4), 2000, pp. 392-396
Citations number
26
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
INORGANIC MATERIALS
ISSN journal
00201685 → ACNP
Volume
36
Issue
4
Year of publication
2000
Pages
392 - 396
Database
ISI
SICI code
0020-1685(200004)36:4<392:DCOIIC>2.0.ZU;2-1
Abstract
Experimental data on the liquidus curve in cadmium fluoride-metal fluoride systems were used to calculate the distribution coefficients of di- and tri valent impurities in CdF2. A similar method was proposed for calculating th e distribution coefficient from solidus data. It was shown that the variati ons of the calculated distribution coefficients with the ionic radii of M2 and R3+ are well fitted by Gaussians. Phase relations in the CdF2-rich par t of the CdF2-InF3 system were studied by differential thermal analysis and x-ray diffraction.