2-Nitrophenylpyruvic acid as a cathode material in a magnesium/zinc-based primary battery

Authors
Citation
R. Renuka, 2-Nitrophenylpyruvic acid as a cathode material in a magnesium/zinc-based primary battery, J APPL ELEC, 30(4), 2000, pp. 483-490
Citations number
40
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF APPLIED ELECTROCHEMISTRY
ISSN journal
0021891X → ACNP
Volume
30
Issue
4
Year of publication
2000
Pages
483 - 490
Database
ISI
SICI code
0021-891X(200004)30:4<483:2AAACM>2.0.ZU;2-5
Abstract
The efficiency of 2-nitrophenylpyruvic acid as a cathode material in a magn esium/zinc based primary battery is examined. The discharge performance of the cell is investigated under different parametric variations such as temp erature, nature of electrolyte, current drain and zeolite modification. A 7 e reduction seems to be responsible for the electrochemical reaction causin g the reduction of 2-nitrophenylpyruvic acid to an indole intermediate whic h is oxidatively cleaved to form anthranilic acid as the end-of-discharge p roduct. Participation of oxygen in the reduction process is indicated. The discharge capacity is 1.03 Ah g(-1), the highest value ever observed in org anic batteries.