Forces between like-charged walls in electrolyte solution: Molecular solvent effects at the McMillan-Mayer level

The force between two like-charged walls immersed in electrolyte solution i s obtained for models that include solvent effects at the McMillan-Mayer (M M) level. In these models the solvent is not represented by discrete partic les but exerts its influence through solvent-averaged ion-ion potentials of mean force which serve as effective potentials. This simplification allows the numerical solution of accurate anisotropic integral equation theories, and the anisotropic hypernetted-chain (AHNC) approximation is used in the present calculations. It is shown that the MM results may differ significan tly from those of the primitive model (PM) which treats the solvent as a di electric continuum. Most interestingly, we find that at the MM level the fo rce between like-charged walls at small separations and with realistic surf ace charges can be attractive for monovalent counterions. This attraction i s due to solvent effects on the effective counterion-counterion interaction and not to the correlated charge fluctuations that give rise to the attrac tions found for divalent counterions in the PM case. The possible relevance of our observations in the interpretation of experimental force measuremen ts is briefly discussed. (C) 2000 American Institute of Physics. [S0021-960 6(00)51720-6].