Soft X-ray emission and absorption spectroscopy of hydrofullerene

Citation
Y. Muramatsu et al., Soft X-ray emission and absorption spectroscopy of hydrofullerene, J ELEC SPEC, 107(2), 2000, pp. 177-184
Citations number
21
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA
ISSN journal
03682048 → ACNP
Volume
107
Issue
2
Year of publication
2000
Pages
177 - 184
Database
ISI
SICI code
0368-2048(200005)107:2<177:SXEAAS>2.0.ZU;2-Q
Abstract
High-resolution soft X-ray emission and absorption spectra in the C K regio n of hydrofullerene, which probably consists mainly of C60H36, were measure d using highly brilliant synchrotron radiation to identify its molecular st ructure and electronic structure. Comparison with the C2p-DOS spectra, calc ulated by discrete variational (DV) X alpha molecular orbital calculations, of three possible C60H36 isomers, showed that the measured X-ray spectra a pproximately agreed with the calculated C2p-DOS spectra of the T-symmetry i somer. The X-ray spectral features were explained by the electronic structu re hybridized between the sp(2) and sp(3) carbon atoms of the T-symmetry C6 0H36. (C) 2000 Elsevier Science B.V. All rights reserved.