1,4-Diionic organophosphorus compounds stereoselective synthesis of dialkyl 2-(1,1,1,5,5,5-hexafluoro-2,4-dioxo-pentane-3-yl-3-yide)-3-triphenylphosphoniobutane-1,4-dioates

Citation
A. Shaabani et al., 1,4-Diionic organophosphorus compounds stereoselective synthesis of dialkyl 2-(1,1,1,5,5,5-hexafluoro-2,4-dioxo-pentane-3-yl-3-yide)-3-triphenylphosphoniobutane-1,4-dioates, J FLUORINE, 103(2), 2000, pp. 155-157
Citations number
18
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF FLUORINE CHEMISTRY
ISSN journal
00221139 → ACNP
Volume
103
Issue
2
Year of publication
2000
Pages
155 - 157
Database
ISI
SICI code
0022-1139(200005)103:2<155:1OCSSO>2.0.ZU;2-E
Abstract
The addition of triphenylphosphine to dialkyl acetylenedicarboxylates in th e presence of 1, 1,1,5,5,5-hexafluoropentane-2,4-dione leading to highly fu nctionalized 1,4-diionic organophosphorus compounds is reported. These stab le crystalline phosphorus betaines were characterized by spectroscopy, mass spectrometry and elemental analysis. (C) 2000 Elsevier Science S.A. All ri ghts reserved.