Coinage metal complexes of 3,5-bis(trifluoromethyl)pyrazolate ligand synthesis and characterization of {[3,5-(CF3)(2)Pz]Cu}(3) and {[3,5-(CF3)(2)PZ]Ag}(3)

Authors
Dias, HVR Polach, SA Wang, ZY
Citation
Hvr. Dias et al., Coinage metal complexes of 3,5-bis(trifluoromethyl)pyrazolate ligand synthesis and characterization of {[3,5-(CF3)(2)Pz]Cu}(3) and {[3,5-(CF3)(2)PZ]Ag}(3), J FLUORINE, 103(2), 2000, pp. 163-169
Citations number
32
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF FLUORINE CHEMISTRY
ISSN journal
00221139 → ACNP
Volume
103
Issue
2
Year of publication
2000
Pages
163 - 169
Database
ISI
SICI code
0022-1139(200005)103:2<163:CMCO3L>2.0.ZU;2-H
Abstract
Copper(I) and silver(I) adducts of [3,5-(CF3)(2)Pz](-) have been prepared i n good yield by reacting the corresponding metal(I) oxide with pyrazole [3, 5-(CF3)(2)Pz]H. H-1, C-13, F-19 NMR spectroscopic data as well as their X-r ay crystal structures are presented. The copper adduct is trimeric in the s olid state. The silver complex exists both as trimers and pairs of trimers, The trimer pairs show weak Ag-Ag interactions (Ag ... Ag distance=3.3073(1 3) Angstrom). (C) 2000 Elsevier Science S.A. All rights reserved.