We studied luminescence properties in PbBr2 crystals under one- and two-pho
ton excitation, and found that a luminescence band at 2.56 eV is intrinsic
in origin. Decay time measurements revealed the exciton relaxation process
in which an exciton is decomposed into a charge-separated pair of a self-tr
apped electron (STEL) and a self-trapped hole (STH). The relaxation process
is ascribed to strong interaction of electrons and holes with phonons. (C)
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