Cathodo- and photoluminescence of MnF2 thin epitaxial layers and MnF2-CaF2
superlattices on Si(1 1 1) has been studied at low temperatures. A blue shi
ft of the main Mn2+ broad band in MnF2 films thinner than three monolayers
is revealed. The shift is likely to be due to the change of the crystal str
ucture from the tetragonal rutile-type characteristic of bulk crystals and
thick layers to the cubic fluorite-type structure, as measured by RHEED and
EXAFS. (C) 2000 Elsevier Science B.V. All rights reserved.