We review recently discovered processes that can lead to the erasure of per
sistent spectral holes burnt via two-step ionization (photochemical hole bu
rning) in doped insulating crystals. These hole erasure processes are based
on photoinduced recharging of ions. Two mechanisms are described here: acc
eptor transitions, which occur in the system Li2Ge7O15 : Cr3+, and electron
tunneling between impurity ions in different charge states, as observed in
CaS : Eu. (C) 2000 Published by Elsevier Science B.V. All rights reserved.