Nv. Desai et al., Role of room-temperature electrochemical oxidation in Pb-doped Bi-Sr-Ca-CuO superconducting thin films, MATER CH PH, 65(1), 2000, pp. 68-73
A room-temperature electrochemical synthesis of Bi(Pb)-Sr-Ca-CuO films onto
silver substrates has been successfully carried out using D.C. electrodepo
sition technique. The various preparative parameters, such as deposition po
tential, current density, etc, have been studied and optimised. The electro
chemical oxidation of these films in alkaline solution (1 N KOH) has been u
sed for preparing the Bi(Pb)-Sr-Ca-CuO superconducting thin films. The film
s are oxidised for different periods and studied for their structural and e
lectrical properties. (C) 2000 Elsevier Science S.A. All rights reserved.