After <9 months of operation in a polyvinyl chloride (PVC) manufacturing pl
ant, alloy 2205 duplex stainless steel (UNS 31803) columns and spiral heat
exchangers (HXs) were corroding and cracking. The columns were repaired and
remained in service but the HXs needed to be replaced. Candidate materials
for the HXs were assessed, and it was found that the super-austenitic allo
ys containing 6% molybdenum would be more appropriate for this application.