Core-polarization effects in CuII

Citation
E. Biemont et al., Core-polarization effects in CuII, PHYS SCR, 61(5), 2000, pp. 567-580
Citations number
31
Categorie Soggetti
Physics
Journal title
PHYSICA SCRIPTA
ISSN journal
02811847 → ACNP
Volume
61
Issue
5
Year of publication
2000
Pages
567 - 580
Database
ISI
SICI code
0281-1847(200005)61:5<567:CEIC>2.0.ZU;2-O
Abstract
Core-polarization and configuration interaction effects are investigated in singly ionized copper. It is shown that these effects are responsible, to a large extent, for the discrepancies observed between recent relativistic Hartree-Pock (HFR) and configuration-interaction (CIV3) calculations and ac curate beam-laser experimental results. A new set of transition rates is ob tained using the HFR + Core Polarization formalism leading to theoretical l ifetime and transition probability values in fair agreement with the experi ment. An indicative calculation performed with the configuration - interact ion code SUPERSTRUCTURE demonstrates the importance of semi-empirical term energy corrections in producing reliable transition rates in a case like th e present one.