T. Akimoto et al., Orbital stability in the spin-ordered phase of bilayer manganites as investigated by neutron-diffraction measurements, PHYS REV B, 61(17), 2000, pp. 11270-11273
Temperature variation of lattice structure has been investigated for ferrom
agnetic La(Sr0.8Ca0.2)(2)Mn2O7 and layered-type (A-type) antiferromagnetic
NdSr2Mn2O7. We have found that distortion of the MnO6 octahedra decreases i
n the spin-ordered phase for both the systems. We further estimated the rel
ative stability of the e(g) orbitals by means of Madelung potential calcula
tion, and discussed the orbital state in the spin-ordered phase.