A number of properties of fluoro polymers in aqueous solutions of hydrogen
halides have been investigated. The results enable fluoropolymers to be use
d in the purification of hydrogen halides and their aqueous solutions. The
hydrophobicity of fluoropolymers and their diffusion permeability enable pr
oduction of hydrogen halides of low moisture content. A second unit for hyd
ro-ionic convection is based on hydro-ionic repulsion (determined by the hy
drophobic properties of the fluoropolymer) and ionic elimination. The two u
nits enable the highly effective, ecologically safe manufacture of highly p
ure hydrogen halides and their aqueous solutions to be carried out with min
imum feedstock, cooling water, and power consumption.