We tried to apply ab initio calculations on large amorphous structure to in
vestigate the origine of the second harmonics generation from silica glass.
We made (Ge doped) (poled) silica glass by molecular dynamics, then we cal
culated the change of the electronic structures of (Ge doped) (poled) silic
a glass under the external strong electric field. The changes of these elec
tronic structures such as density of states and electron distribution, were
small within our approximal;ion.