Application of anodic dissolution method for a study of electrocolored aluminum oxides

Citation
A. Jagminas et J. Giedraitiene, Application of anodic dissolution method for a study of electrocolored aluminum oxides, RUSS J ELEC, 36(4), 2000, pp. 413-416
Citations number
10
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
RUSSIAN JOURNAL OF ELECTROCHEMISTRY
ISSN journal
10231935 → ACNP
Volume
36
Issue
4
Year of publication
2000
Pages
413 - 416
Database
ISI
SICI code
1023-1935(200004)36:4<413:AOADMF>2.0.ZU;2-8
Abstract
The anodic dissolution of color carrier of colored aluminum anodic oxide fi lms (AOF) is studied before and after their coloring, using ac in various e lectrolytes containing Cu(II). The voltammetric polarization curves of anod ic dissolution of colored AOF in 0.1 M H2SO4 depend on the amount of copper deposited in the pores and its oxidation state (Cu, Cu2O, CuO). Analytical and X-ray diffraction examination of AOF prior to and after the anodic dis solution shows that the anodic dissolution method is inapplicable for the d etermination of the oxidation state of copper electrodeposited in AOF pores or the amount of copper oxides.