A comparison of physicochemical properties of hematite ore with octyl hydro
xamic acid and sodium oleate collectors has been made in order to describe
the mechanism of interactions that control adsorption at the solid/liquid i
nterface and to establish the relative selectivity and specificity. The phy
sicochemical properties studied in this investigation, electrokinetics, ads
orption, and microflotation, showed the preferential selectivity of octyl h
ydroxamic acid over sodium oleate. The results exhibited some differences a
nd similarities in their physicochemical behaviors by which the efficiency
of adsorption onto hematite and other oxide surfaces can be qualitatively m
odulated.