In situ NMR observation of tin trichloride-activated rhodium dihydride complexes using parahydrogen induced polarization

Authors
Koch, A Ulrich, C Bargon, J
Citation
A. Koch et al., In situ NMR observation of tin trichloride-activated rhodium dihydride complexes using parahydrogen induced polarization, TETRAHEDRON, 56(20), 2000, pp. 3177-3179
Citations number
13
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON
ISSN journal
00404020 → ACNP
Volume
56
Issue
20
Year of publication
2000
Pages
3177 - 3179
Database
ISI
SICI code
0040-4020(20000512)56:20<3177:ISNOOT>2.0.ZU;2-I
Abstract
Starting from the binuclear complex [RhCl(CO2)](2) in the presence of the p hosphines L=PMe3, PMe2Ph, and PMePh2 various mononuclear dihydrides of the type Rh(H)(2)(SnCl3)L-3 have been obtained upon the addition of parahydroge n, and their H-1 NMR spectra have been investigated using ParaHydrogen Indu ced Polarization (PHIP). (C) 2000 Elsevier Science Ltd. All rights reserved .