Synthetic uses of thioesters of trifluoromethylated acids. Part 2. Reactions with alkenes

Authors
Billard, T Rogues, N Langlois, BR
Citation
T. Billard et al., Synthetic uses of thioesters of trifluoromethylated acids. Part 2. Reactions with alkenes, TETRAHEDR L, 41(17), 2000, pp. 3069-3072
Citations number
10
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
41
Issue
17
Year of publication
2000
Pages
3069 - 3072
Database
ISI
SICI code
0040-4039(20000422)41:17<3069:SUOTOT>2.0.ZU;2-3
Abstract
The photolysis of trifluoromethanethiosulfonates (CF3SO2SR) or trifluorothi oacetates (CF3COSR) in the presence of alkenes provides (trifluoromethyl)al kanes or beta-sulfanyl (trifluoromethyl)alkanes. The formation of these com pounds can be controlled by the nature and the ratio of the reactants. (C) 2000 Published by Elsevier Science Ltd. All rights reserved.