Intramolecular binding site organization by Pd(II) complexation with a resorcin[4]arene derivative

Authors
Lim, CW Hong, JI
Citation
Cw. Lim et Ji. Hong, Intramolecular binding site organization by Pd(II) complexation with a resorcin[4]arene derivative, TETRAHEDR L, 41(17), 2000, pp. 3113-3117
Citations number
31
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
41
Issue
17
Year of publication
2000
Pages
3113 - 3117
Database
ISI
SICI code
0040-4039(20000422)41:17<3113:IBSOBP>2.0.ZU;2-F
Abstract
Intramolecular assembly of a binding site by Pd(II) ion complexation with a resorcin[4]arene derivative has led to a water-soluble resorcin[4]arene re ceptor. The bowl-shaped cavitand host 2 shows a good binding affinity to ar omatic carboxylates with alkyl moiety of an appropriate length in D2O. The guest inclusion within the host cavity was confirmed by H-1 NMR spectroscop y. Hydrophobic and electrostatic interactions turned out to act as cooperat ive binding force for a strong complex formation with appropriate anionic g uests in water. (C) 2000 Elsevier Science Ltd. Air rights reserved.